Thanks for your replies.
Sorry, it seems to be a bug/feature in the XReader (PDF reader) software I am using.
By the way, although my main computer is an iMac, as in my signature, these documents are being made and printed on LinuxMint 19 using LibreOffice 6.0.7.3.
I was viewing and printing the PDFs using XReader 1.8.5, but in future I will use LO Draw.
More details:
I was talking about physical printed (or screen) size, not file size.
I used the built-in PDF Export.
Zizi64, I thought you were on the right track.
The documents have non-standard margins, to get them, I had to over-ride LO advice that they were outside the print area.
So I have tested with a document modified to have default 2cm margins all round.
But, to my surprise, the document is still reduced in size.
My measurements show the reduction is nearer 91.5% - the reduction is similar on screen (viewed at 100%) and when printed.
But, if I open the PDF in LibreOffice, it opens in Draw and is not reduced in size when viewed at 100% and when printed.